Oppenauer 氧化

    仲醇在叔丁醇铝或异丙醇铝和丙酮作用下，氧化成为相应的酮，而丙酮则还原为异丙醇。这个反应相当于Meerwein-Ponndorf反应的逆向反应。

反应机理

反应实例

参考文献

[1] R. V. Oppenauer, Rec. Trav. Chim. 56, 137 (1937).

[2] T. Bersin in Newer Methods of Preparative Organic Chemistry, English Ed. (Interscience, New York, 1948), p 125;

[3] C.Djerassi in Organic Reactions 6, 207 (1951)

[4] W. A. Waters in H. Gilman, Organic Chemistry vol. 4 (John Wiley & Sons, New York, 1953), p1238